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Three-fold interpenetrating three-dimensional networks based on C-methylcalix[4]resorcinarene incorporating
1Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260-3000, USA.
Abstract:
A new solid based on C-methylcalix[4]resorcinarene and the linker molecule bis(4-pyridylmethylidyne)hydrazine (bpmh) has been prepared, in which brick-wall sheets are linked in the third dimension to give networks with three intersecting perpendicular channels; the networks interpenetrate three-fold, but nevertheless leave cavities capable of including sizable guest molecules.