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Synthesis of an F-H gambierol subunit using a C-glycoside-centered strategy
Utpal Majumder1, Jason M Cox, Jon D Rainier
1Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
Organic Letters
|March 14, 2003
Abstract:
[structure: see text] This manuscript describes our synthesis of the F-H subunit of gambierol. In addition to the synthesis of the tricycle, of note is an interesting protecting group influence on the generation of a C(23) C-glycoside as well as the use of ring-closing metathesis to generate a tetrasubstituted enol ether.