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35Cl quadrupolar constants obtained by solid-state NMR: study of chlorinated Al-O-P clusters, involving OH...Cl
T Azaïs1, C Bonhomme, M E Smith
1Laboratoire de Chimie de la Matière Condensée, Université P et M Curie, 4, Place Jussieu, 75252 Paris Cedex, France.
Solid State Nuclear Magnetic Resonance
|March 14, 2003
Abstract:
Simulation of static and MAS NMR spectra obtained at high field (B(0) = 14.08 T) and high spinning frequency (up to nu(rot) = 22 kHz) allows the determination of 35Cl quadrupolar parameters for various cubane-shaped, cage-like and cyclic Al-O-P clusters; the role of OH...Cl contacts is emphasized.