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Tetraphenylphosphonium 4-hydroxy-2,2,6,6-tetramethylpiperidinyloxy-4-sulfonate
Hiroki Akutsu1, Jun Ichi Yamada, Shin'ichi Nakatsuji
1Department of Material Science, Graduate School of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan. akutsu@sci.himeji-tech.ac.jp
Abstract:
The title compound, C(24)H(20)P(+).C(9)H(17)NO(5)S(-), consists of an organic monovalent cation and an organic monovalent anion, the latter being derived from the TEMPO radical (TEMPO is 2,2,6,6-tetramethylpiperidin-1-oxyl). Two inversion-related anions interact via two -O-H.O-S- hydrogen bonds, forming a dimer in which there are no short contacts between the spin centres (-N-O) of the TEMPO(OH)SO(3)(-) anions. Furthermore, no significant magnetic interaction is observed between the dimers because the dimer is surrounded by cations. These results are consistent with the paramagnetic behaviour of the title salt.