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Mannose derived hexacoordinated phosphate--a generally efficient chiral anion for asymmetric applications
Céline Pérollier1, Samuel Constant, Jonathan J Jodry
1Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland.
Chemical Communications (Cambridge, England)
|August 26, 2003
Abstract:
Mannose derived hexacoordinated phosphate--prepared in two steps from methyl-alpha-D-mannopyranoside--is a chiral anionic auxiliary with broad asymmetric efficiency.