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A forbidden rearrangement

Martin Leivers1, Iris Tam, Kevin Groves

  • 1Department of Chemistry, Columbia University, New York, New York 10027, USA.

Organic Letters
|September 12, 2003
PubMed
Summary

Barrelene derivatives undergo fragmentation to yield benzene and cyanocyclopropenes. The barrelene anion rearranges via a formally forbidden cyclopropyl ring cleavage, forming an allyl anion.

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