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Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity
Tatsuya Fujii1, Asako Naito, Syuhei Yamaguchi
1Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.
Chemical Communications (Cambridge, England)
|December 3, 2003
Abstract:
A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which has exhibited a higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that with a trigonal-bipyramidal one.