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Ultrafast dynamics of Cu(I)-phenanthrolines in dichloromethane
Tissa Gunaratne1, Michael A J Rodgers, Delphine Felder
1Department of Chemistry, Bowling Green State University, Bowling Green, Ohio 43403, USA.
Chemical Communications (Cambridge, England)
|January 6, 2004
Abstract:
Transient absorption spectrometry of Cu(I)-phenanthrolines in CH2Cl2 reveals ligand-independent dynamic processes lasting 15 ps, which are associated with the peculiar structural rearrangements occurring for this class of compounds upon photoexcitation.