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Comparison of photoelectron transfer in solution and the solid state for two intervalence radical cations
Stephen F Nelsen1, Asgeir E Konradsson, Edward L Clennan
1Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706-1396, USA. nelsen@chem.wisc.edu
Organic Letters
|January 16, 2004
Abstract:
[structure: see text] The optical diffuse reflectance and solution spectra of two bis-hydrazine radical cationic intervalence compounds have been compared. The results are consistent with an ion-pairing increase and an "effective polarity" in these crystals that is not far from that of acetonitrile or other polar solvents.