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Slow regions percolate near glass transition
1Department of Physics, Faculty of Sciences and Letters, Istanbul Technical University, Maslak 80626, Istanbul, Turkey.
The European Physical Journal. E, Soft Matter
|March 12, 2004
Abstract:
A nanosecond scale in situ probe reveals that a bulk linear polymer undergoes a sharp phase transition as a function of the degree of conversion, as it nears the glass transition. The scaling behaviour is in the same universality class as percolation. The exponents gamma and beta are found to be 1.7 +/- 0.1 and 0.41 +/- 0.01 in agreement with the best percolation results in three dimensions.