Related Experiment Video
Updated: Aug 6, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Thermotropic biaxial nematic liquid crystals
L A Madsen1, T J Dingemans, M Nakata
1Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA.
Abstract:
We have synthesized liquid crystal (LC) mesogens based on a nonlinear oxadiazole unit that exhibit nematic phases near 200 degrees C. Polarized microscopy and conoscopy indicate that these LCs are biaxial nematics. Unambiguous and quantitative evidence for biaxiality is achieved using 2H NMR spectroscopy. "2D powder" spectra, obtained by rotating 2H-labeled samples about an axis perpendicular to the magnetic field at approximately 200 Hz, yield phase biaxiality parameters of approximately 0.1 when coupled with rigorous and proven simulations.
Related Concept Videos
Fluid Mosaic Model
Membrane Fluidity
Structures of Solids
Properties of Enantiomers and Optical Activity
Thermal Electrocyclic Reactions: Stereochemistry
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
Nonideal Two-Component Liquid Solutions

