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Related Experiment Videos

Comparative study on adhesive performance of functional monomers.

Y Yoshida1, K Nagakane, R Fukuda

  • 1Department of Biomaterials, Okayama University Graduate School of Medicine and Dentistry, 2-5-1 Shikata-cho, Okayama 700-8525, Japan.

Journal of Dental Research
|May 22, 2004
PubMed
Summary
This summary is machine-generated.

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Mild self-etching dental adhesives bond better through chemical interactions. The functional monomer 10-methacryloxydecyl dihydrogen phosphate (10-MDP) shows strong chemical bonding to hydroxyapatite, enhancing adhesive performance beyond micro-mechanical interlocking.

Area of Science:

  • Biomaterials Science
  • Dental Materials Science
  • Adhesion Science

Background:

  • Mild self-etch adhesives create a hybrid layer with residual hydroxyapatite.
  • This hydroxyapatite may facilitate chemical interactions with functional monomers.
  • Such interactions could improve adhesive performance beyond micromechanical retention.

Purpose of the Study:

  • To investigate the chemical interaction between functional monomers and hydroxyapatite.
  • To evaluate the adhesive potential of specific functional monomers to dentin.
  • To elucidate the role of residual hydroxyapatite in adhesive bonding.

Main Methods:

  • X-ray photoelectron spectroscopy and atomic absorption spectrophotometry were used to characterize monomer-hydroxyapatite interactions.

Related Experiment Videos

  • Transmission electron microscopy was employed for ultra-morphological analysis of monomer-dentin interactions.
  • Dissolution rate of monomer calcium salts was assessed to confirm bond stability.
  • Main Results:

    • 10-methacryloxydecyl dihydrogen phosphate (10-MDP) demonstrated strong adhesion to hydroxyapatite with stable bonding.
    • 4-methacryloxyethyl trimellitic acid (4-MET) exhibited significantly lower bonding potential.
    • 2-methacryloxyethyl phenyl hydrogen phosphate (phenyl-P) showed hydrolytically unstable bonding to hydroxyapatite.

    Conclusions:

    • Functional monomers can chemically bond with residual hydroxyapatite in the hybrid layer.
    • This chemical interaction contributes to the overall adhesive potential of dental materials.
    • 10-MDP possesses superior chemical bonding efficacy to hydroxyapatite compared to other tested monomers.