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The first slipped pseudo-quadruple-decker complex of phthalocyanines
Hongchuan Zhang1, Rongmin Wang, Peihua Zhu
1Department of Chemistry, Shandong University, Jinan 250100, China.
Inorganic Chemistry
|July 20, 2004
Abstract:
The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatment of the protonated double-decker SmIIIH(Pc)[Pc(alpha-OC4H9)8] with NaOH. The supramolecular structure contains two double-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in which an aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand.
