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Related Experiment Videos

Bis[N,N-bis(2-hydroxyethyl)dithiocarbamato]dimethyltin(IV).

S W Ng1, A A Yang Farina, A H Othman

  • 1Institute of Postgraduate Studies and Research, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Acta Crystallographica. Section C, Crystal Structure Communications
|July 21, 2004
PubMed
Summary

This study details the crystal structure of a novel tin compound, [Sn(CH(3))(2)(C(5)H(10)NO(2)S(2))(2)]. The compound exhibits unique tetrahedral geometry distorted by intramolecular tin-sulfur bonds and forms linear chains via hydrogen bonds.

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Area of Science:

  • Organometallic Chemistry
  • Crystallography
  • Coordination Chemistry

Background:

  • Organotin compounds are versatile in synthesis and catalysis.
  • Understanding the solid-state structure is crucial for predicting reactivity.
  • Tin's coordination chemistry offers diverse structural motifs.

Purpose of the Study:

  • To elucidate the crystal structure of the title tin compound.
  • To investigate the coordination geometry around the tin center.
  • To identify intermolecular interactions influencing the solid-state packing.

Main Methods:

  • Single-crystal X-ray diffraction analysis.
  • Crystallographic symmetry analysis.
  • Bond length and angle measurements.

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Main Results:

  • The compound [Sn(CH(3))(2)(C(5)H(10)NO(2)S(2))(2)] displays crystallographic mirror symmetry.
  • The tin atom's coordination polyhedron is a tetrahedron distorted towards a skew-trapezoidal bipyramid due to an intramolecular Sn-S contact.
  • Molecules are arranged in linear chains mediated by intermolecular O-H-O hydrogen bonds.

Conclusions:

  • The observed coordination geometry highlights the influence of intramolecular interactions on tin's coordination sphere.
  • Intermolecular hydrogen bonding dictates the extended chain structure in the solid state.
  • This structural characterization provides a foundation for further studies on the properties and applications of this organotin complex.