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A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 4(9).6(6) net
1Department of Chemistry, University of Puerto Rico, Rio Piedras Campus, PO Box 23346, San Juan, PR 00931, USA.
Chemical Communications (Cambridge, England)
|September 16, 2004
Abstract:
The reactions of silver(i) salts with 3,5-diphenyl-1,2,4-triazole result in three-dimensional, porous, cationic metal-organic frameworks based on novel 6-connected, trigonal-prismatic, pentanuclear silver-triazolate clusters, interconnected by linear N-Ag-N linkers; this robust water- and organic-insoluble structure exhibits both nonpolar-solvent adsorption and anion-exchange properties.
