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Velocity distributions remotely measured with a single-sided NMR sensor
F Casanova1, J Perlo, B Blümich
1Institut für Technische und Makromolekulare Chemie, RWTH Aachen, D-52056, Germany.
Journal of Magnetic Resonance (San Diego, Calif. : 1997)
|October 27, 2004
Summary
This study introduces a novel pulsed field gradient nuclear magnetic resonance (PFG NMR) method for measuring velocity distributions ex situ using single-sided NMR sensors. The technique overcomes limitations of conventional magnets, enabling new applications in fluid dynamics.
Area of Science:
- Nuclear Magnetic Resonance Spectroscopy
- Fluid Dynamics
- Analytical Chemistry
Background:
- Pulsed field gradient nuclear magnetic resonance (PFG NMR) is a key technique for measuring molecular displacement.
- Conventional NMR magnets have restricted geometry, limiting applications for flow measurements.
- Single-sided NMR sensors offer an open geometry, enabling broader NMR applications.
Purpose of the Study:
- To present the first approach for measuring velocity distributions ex situ using PFG NMR on a single-sided NMR sensor.
- To address distortions in displacement encoding caused by inhomogeneous fields in PFG NMR.
- To demonstrate a novel method for remote velocity distribution measurement.
Main Methods:
- Implementation of a pulsed field gradient sequence on a single-sided NMR sensor.
- Numerical simulations to analyze and correct for field distortions (B0 and B1).
- Combination of an alternating stimulated spin-echo PFG sequence with a multi-echo acquisition scheme.
Main Results:
- Demonstration of corrected displacement encoding in the presence of inhomogeneous fields.
- Significant increase in method sensitivity through a multi-echo acquisition scheme.
- Successful measurement of velocity propagator in laminar flow with good agreement to theory.
Conclusions:
- Single-sided NMR sensors can be effectively used for ex situ velocity distribution measurements.
- The proposed PFG NMR sequence and correction methods overcome limitations of conventional NMR.
- This technique expands the applicability of NMR for studying fluid flow in previously inaccessible systems.