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Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
Published on: February 23, 2017
System zones in capillary zone electrophoresis: moving boundaries caused by freely migrating hydroxide ions
Jozef L Beckers1, Marek Urbánek, Petr Bocek
1Eindhoven University of Technology, Department of Chemistry, Eindhoven, The Netherlands.
Abstract:
We present theoretical and experimental data indicating that anionic system zones (SZs), due to free migrating hydroxide anions, can be expected in background electrolytes (BGEs) with a low buffer capacity. In the system containing completely unbuffered BGEs the hydroxide ions derived from the sample start to migrate freely through the capillary tube with the mobility of single hydroxide ions and cause stepwise disturbances in the baseline of the detector trace. Remarkably, this type of SZs do not appear to contribute significantly to the electromigration dispersion (EMD) of the zones of the analytes.
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