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Visual sensing of Ca2+ ion via photoreaction of fluorenyl ester-armed cyclen

Tomoko N Player1, Satoshi Shinoda, Hiroshi Tsukube

  • 1Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan.

Organic & Biomolecular Chemistry
|April 29, 2005
PubMed

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Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation