Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

An eta(6)-dienyne transition-metal complex.

Joseph M O'connor1, Seth J Friese, Betsy L Rodgers

  • 1Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. jmoconnor@ucsd.edu

Journal of the American Chemical Society
|June 30, 2005
PubMed
Summary

Ruthenium complexes reacted with chloro-vinyl-alkynyl cyclopentenes to form novel indenyl-ruthenium complexes. X-ray crystallography confirmed the structures of key indenyl-ruthenium products, showcasing new organometallic compounds.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Heterotrimetallic {LnOVPt} complexes with antiferromagnetic Ln-V coupling and magnetic memory.

Chemical communications (Cambridge, England)·2020
Same author

Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure.

Inorganic chemistry·2020
Same author

Fluorous Soluble Cyanine Dyes for Visualizing Perfluorocarbons in Living Systems.

Journal of the American Chemical Society·2020
Same author

Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles.

The Journal of organic chemistry·2020
Same author

Luminescence of Lanthanide Complexes with Perfluorinated Alkoxide Ligands.

Inorganic chemistry·2020
Same author

Synthesis of Anhydroryanodol.

Journal of the American Chemical Society·2020

Area of Science:

  • Organometallic Chemistry
  • Synthetic Chemistry
  • Catalysis

Background:

  • Ruthenium complexes are versatile catalysts in organic synthesis.
  • Cyclopentene derivatives offer unique structural motifs for ligand design.

Purpose of the Study:

  • To synthesize and characterize novel ruthenium complexes with indenyl ligands.
  • To explore the reactivity of ruthenium complexes with functionalized cyclopentene derivatives.

Main Methods:

  • Reaction of [(eta5-C5R5)Ru(CH3CN)3]PF6 complexes with chloro-vinyl-alkynyl cyclopentenes.
  • Characterization of products using 1H NMR spectroscopy and X-ray crystallography.

Main Results:

  • Formation of (eta5-C5R5)Ru[eta6-(5-chloro-4-methyl-6-propylindan)]PF6 and (eta5-C5R5)Ru(eta6-4-methyl-6-propylindan)]PF6 complexes.

Related Experiment Videos

  • Observation of an eta6-dienyne complex, (eta5-C5Me5)Ru[eta6-(1-isopropenyl-2-pent-1-ynylcyclopentene)]PF6, at low temperatures.
  • Structural confirmation of key complexes via X-ray crystallography.

    • Conclusions:

    • The study successfully synthesized novel indenyl-ruthenium complexes through reactions with functionalized cyclopentenes.
    • The findings demonstrate the utility of ruthenium complexes in constructing complex organometallic structures.