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Synthetic studies on sugar-fused erinacines
Ayato Sato1, Tomoya Masuda, Hirokazu Arimoto
1Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Organic & Biomolecular Chemistry
|July 13, 2005
Abstract:
Samarium-mediated 7-endo-trig radical cyclization afforded excellent stereocontrol of the four contiguous asymmetric centers present in the 6-7-6 tricyclic cores of the (sugar-fused) erinacines E, F, and G.
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