Related Experiment Video
Updated: Aug 15, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
Published on: July 28, 2022
Isobaric vapor-liquid equilibrium for methyldichlorosilane-dimethyldichlorosilane-benzene system
Zu-Min Qiu1, Xin-Liang Xie, Shu-Xian Yu
1School of Environmental Science and Engineering, Nanchang University, Nanchang 330029, China. qiuzm@ncu.edu.cn
Abstract:
The elucidation of vapor-liquid equilibrium (VLE) of the halogenated silane was necessary for the production of silicon derivatives, especially for methylvinyldichlorosilane, due to the lack of the relevant reports. Isobaric VLE for the system methyldichlorosilane-dimethyldichlorosilane-benzene and isobaric VLE of the three binary systems were measured with a new pump-ebulliometer at the pressure of 101.325 kPa. These binary compositions of the equilibrium vapor were calculated according to the Q function of molar excess Gibbs energy by the indirect method and the resulted VLE data agreed well with the thermodynamic consistency. Moreover, the experimental data were correlated with the Wilson, NRTL, Margules and van Laar equations by means of the least-squares fit, the acquired optimal interaction parameters were fitted to experimental vapor-liquid equilibrium data for binary systems. The binary parameters of Wilson equation were also used to calculate the bubble point temperature and the vapor phase composition for the ternary mixtures without any additional adjustment. The predicted vapor-liquid equilibrium for the ternary system was in a good agreement with the experimental results. The VLE of binary and multilateral systems provided essential theory for the production of the halogenated silane.
Related Concept Videos
Phase Diagrams of Ternary Systems
Ideal Solutions or Mixtures
Two Components: Liquid–Liquid Systems
Distillation: Vapor–Liquid Equilibria
Ideal Solutions
Nonideal Two-Component Liquid Solutions

