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Updated: Aug 15, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Polymer building blocks: self-assembly of silver(I) cyclotriphosphazene cationic columns
Eric W Ainscough1, Andrew M Brodie, Craig V Depree
1Chemistry-Institute of Fundamental Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand.
Abstract:
The multimodal ligand hexakis(2-pyridyloxy)cyclotriphosphazene (L) and its 4-methyl-2-pyridyloxy analogue (MeL) react with Ag(I) to afford {[AgL]+}infinity supramolecular cationic columns via self-assembly, with the anions occupying the intercolumnar channels. In contrast, the reaction of MeL with Cu(I) yields a dimetallic Cu(II) complex containing mu-OH and mu-4-methyl-2-pyridyloxylato bridges.
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