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Updated: Aug 13, 2026
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Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018
A 3D porous lanthanide-fumarate framework with water hexamer occupied cavities, exhibiting a reversible dehydration
Wen-Hua Zhu1, Zhe-Ming Wang, Song Gao
1State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, PR China.
Dalton Transactions (Cambridge, England : 2003)
|January 27, 2006
Abstract:
[Sm2(fumarate)3(H2O)4] x 3 H2O, a new porous pillared layer framework with 0D cavities for the accommodation of chair-like hexameric water clusters, possesses three kinds of fumarate ligand with their two COO ends adopting different coordination modes and shows reversible de- and re-hydration behavior.
