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Updated: Aug 11, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Novel weak coordination to silylium ions: formation of nearly linear Si-H-Si bonds
Stephan P Hoffmann1, Tsuyoshi Kato, Fook S Tham
1Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California 92521, USA.
Abstract:
The weakly coordinating carborane anion in ion-like trialkylsilyl species R3Si(CHB11Cl11) can be displaced by nucleophiles as weak as ortho-dichlorobenzene, SO2 and trialkylsilanes, the latter forming nearly linear hydride bridges in R3Si-H-SiR3+ cations.
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