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Updated: Aug 7, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes
Pierre de Frémont1, Edwin D Stevens, Manuel R Fructos
1Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148, USA.
Abstract:
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.
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