Related Experiment Video
Updated: Aug 7, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Similarities in the Cp/T3 peaks in amorphous and crystalline metals
D J Safarik1, R B Schwarz, M F Hundley
1Materials Science and Technology Division, Los Alamos National Laboratory, New Mexico 87545, USA.
Abstract:
A low-temperature peak in C(p)/T(3) vs is ubiquitous to glasses. It arises from an abundance of low-frequency vibrations, the origin of which remains unclear. A comparable C(p)/T(3) vs peak is observed in crystals due to the dispersion of acoustic phonons and/or the excitation of optical phonons. We compared the C(p)/T(3) vs peaks in metallic and oxide glasses to elemental crystals by analyzing specific heat, phonon density of states, and elastic constant data. We observe no clear distinction in the peak temperature or amplitude between metallic glasses and crystals. Surprisingly, the peak is larger in single crystal Pd(40)Cu(40)P(20) than in glassy Pd(40)Cu(40)P(20).
More Related Videos
06:35Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
07:24Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
Published on: May 10, 2021
Related Concept Videos
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Polymer Classification: Crystallinity
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Structures of Solids
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations