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Updated: Aug 6, 2026

06:53
Fabrication and Optimization of Type II Silicon Clathrate Films
Published on: October 14, 2025
Novel pi-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation
Peter Jutzi1, Andreas Mix, Beate Neumann
1Department of Chemistry, University of Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld, Germany. peter.jutzi@uni-bielefeld.de
Abstract:
The pentamethylcyclopentadienylsilicon(II) cation, Me5C5Si+, opens up access to novel silicocene derivatives; the penta-iso-propylcyclopentadienylsilicon(II) cation, iPr5C5Si+, is obtained by reaction of the mixed silicocene (iPr5C5)(Me5C5)Si with H(OEt2)2+ Al[OC(CF3)3]4-.
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