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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Oxidative generation of diarylcarbenium ion pools

Masayuki Okajima1, Kazuya Soga, Toshiki Nokami

  • 1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.

Organic Letters
|October 20, 2006
PubMed
Summary

Researchers generated diarylcarbenium ion pools via anodic oxidation of diarylmethanes. These reactive intermediates undergo reactions with nucleophiles and reductive homocoupling, enabling further transformations.

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