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Updated: Jul 18, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

Toroidal hopping of a single hole through the circularly-arrayed naphthyl groups in hexanaphthylbenzene cation

Vincent J Chebny1, Ruchi Shukla, Rajendra Rathore

  • 1Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin 53201-1881, USA.

The Journal of Physical Chemistry. A
|December 1, 2006
PubMed
Summary

Researchers synthesized a propeller-shaped molecule with six naphthyl groups. Its cation radical shows a charge-resonance transition, indicating electron transfer across the redox centers.

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