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Dynamic combinatorial resolution: direct asymmetric lipase-mediated screening of a dynamic nitroaldol library

Pornrapee Vongvilai1, Marcus Angelin, Rikard Larsson

  • 1Department of Chemistry, KTH-Royal Institute of Technology, Teknikringen 30, 10044 Stockholm, Sweden.

Angewandte Chemie (International Ed. in English)
|December 16, 2006
PubMed
Abstract

No abstract available in PubMed .

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Crossed Aldol Reaction Using Strong Bases: Directed Aldol Reaction

The reaction between two different carbonyl compounds comprising α hydrogen in the presence of a strong base like lithium diisopropylamide (LDA) to form a crossed aldol product is known as a directed aldol reaction. The directed aldol reaction is depicted in Figure 1.