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Lanthanide reagents in solid phase synthesis.

Lisa A Sloan1, David J Procter

  • 1School of Chemistry, Oxford Road, The University of Manchester, Manchester, UK.

Chemical Society Reviews
|January 18, 2007
PubMed
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Lanthanide reagents are increasingly used in solid-phase synthesis. This review covers lanthanide(III) Lewis acids, lanthanide(IV) oxidants, and highlights the growing application of lanthanide(II) species.

Area of Science:

  • Organic Chemistry
  • Catalysis
  • Materials Science

Background:

  • Lanthanide reagents are emerging as versatile tools in organic synthesis.
  • Solid-phase synthesis offers advantages in purification and automation.

Purpose of the Study:

  • To review the application of lanthanide reagents in solid-phase organic synthesis.
  • To highlight the utility of lanthanide(II) species in this field.

Main Methods:

  • Introduction to lanthanide(III) Lewis acids in solid-phase chemistry.
  • Discussion of lanthanide(IV) oxidants in solid-phase reactions.
  • Focus on lanthanide(II) reagents for electron transfer-mediated cleavage.

Main Results:

  • Solid-supported ytterbium(III) catalysts demonstrate efficacy.

Related Experiment Videos

  • Samarium(II) species enable linker cleavage via electron transfer.
  • Lanthanide reagents offer diverse functionalities in solid-phase synthesis.

    • Conclusions:

    • Lanthanide reagents, particularly lanthanide(II) species, are becoming integral to solid-phase organic synthesis.
    • The unique properties of lanthanides enable novel synthetic strategies on solid supports.