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Updated: Jul 16, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Chemistry of pnictogen(III)-nitrogen ring systems
Maravanji S Balakrishna1, Dana J Eisler, Tristram Chivers
1Department of Chemistry, University of Calgary, Calgary, Alberta, Canada T2N 1N4.
Abstract:
This critical review covers significant recent advances in the chemistry of pnictogen(III)-nitrogen ring systems, also known as cyclopnict(III)azanes. The synthetic methodologies and reactions of the heavier pnictogen systems are compared with the well-developed chemistry of cyclophosph(III)azanes. Particular attention is focused on ring-oligomerization processes and the use of four-membered E(2)N(2) rings as building blocks for the synthesis of macrocyclic molecules. Main-group element and transition-metal complexes are also discussed (95 references).
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