Deacylation studies on furanose triesters using an immobilized lipase: synthesis of a key precursor for
Ashok K Prasad1, Neerja Kalra, Yogesh Yadav
1Bioorganic Laboratory, Department of Chemistry, University of Delhi, Delhi 110 007, India.
Chemical Communications (Cambridge, England)
|June 21, 2007
Abstract:
Lipozyme TL IM immobilized on silica catalyses the deacylation of 4-C-acyloxymethyl-3,5-di-O-acyl-1,2-O-(1-methylethylidene)-beta-L-threo-pentofuranose to form 3,5-di-O-acyl-4-C-hydroxymethyl-1,2-O-(1-methylethylidene)-alpha-d-xylo-pentofuranose in a highly selective and efficient manner.
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