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Updated: Jul 14, 2026

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
Published on: May 15, 2018
Singly-bonded fullerene dimers: neutral (C(60)Cl(5))(2) and cationic (C(70))(2)(2+)
Sergey I Troyanov1, Erhard Kemnitz
1Department of Chemistry, Moscow State University, Moscow, Russia. stroyano@thermo.chem.msu.ru
Abstract:
C(60)Br(24) and C(70)Br(10) react with TiCl(4), splitting out bromine, and, after Br/Cl exchange, forming singly-bonded dimeric structures (C(60)Cl(5))(2) and [(C(70))(2)](Ti(3)Cl(13))(2), respectively, the latter consisting of dimeric [(C(70))(2)](2+) dications and (Ti(3)Cl(13))(-) anions.
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