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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Published on: October 18, 2019

A well-defined silica-supported dinuclear tungsten(III) amido species: synthesis, characterization and reactivity

Régis M Gauvin1, Olivier Coutelier, Elise Berrier

  • 1Unité de Catalyse et de Chimie du Solide, UMR 8181 CNRS, ENSCL, BP 90108, 59652 Villeneuve d'Ascq Cedex, France. regis.gauvin@ensc-lille.fr

Dalton Transactions (Cambridge, England : 2003)
|July 20, 2007
PubMed

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...