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Published on: October 15, 2015
Effect of pH on anoxic sulfide oxidizing reactor performance
Qaisar Mahmood1, Ping Zheng, Yousaf Hayat
1Department of Environmental Engineering, Zhejiang University, Hangzhou 310029, China.
The anoxic sulfide oxidizing (ASO) reactor performs optimally between pH 5-11. Acidic conditions (pH 3) severely inhibit bacterial communities, while high bisulfide, nitrite, or sulfate levels also reduce efficiency.
Area of Science:
- Environmental microbiology
- Wastewater treatment engineering
Background:
- Anoxic sulfide oxidizing (ASO) reactors are crucial for removing sulfide from wastewater.
- Understanding the impact of pH on ASO reactor performance is vital for optimizing treatment processes.
Purpose of the Study:
- To evaluate the effects of varying pH levels on the performance of anoxic sulfide oxidizing (ASO) reactors.
- To determine the optimal pH range for efficient sulfide and nitrite removal in ASO systems.
Main Methods:
- ASO reactor performance was assessed across a wide influent pH range (4-11).
- Operational conditions, including loading and hydraulic retention time (HRT) tests, were varied.
- Sulfide and nitrite removal rates, along with sulfate formation, were monitored.
Main Results:
- Sulfide oxidation was partial at pH 7-7.5 during loading and HRT tests.
- Bacterial communities showed higher sensitivity to acidic pH (e.g., pH 3) than alkaline conditions.
- Inhibition of sulfide oxidation occurred under highly acidic and alkaline conditions due to high dissolved bisulfide ions, nitrite, and excess sulfate (>300 mg/L).
Conclusions:
- The ASO reactor can be effectively operated within a broad pH range of 5-11, based on sulfide and nitrite removal efficiencies.
- Acidic conditions pose a significant challenge to ASO reactor performance.
- Optimizing influent conditions to manage bisulfide, nitrite, and sulfate levels is important for maintaining efficiency across the operational pH range.
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