Enantioselective hydroxylation of nitroalkenes: an organocatalytic approach
Peter Dinér1, Martin Nielsen, Søren Bertelsen
1Danish National Research Foundation: Center for Catalysis, Department of Chemistry, Aarhus University, Aarhus C, DK-8000, Denmark.
Chemical Communications (Cambridge, England)
|August 31, 2007
Abstract:
An easy hydroxylation of aliphatic nitroalkenes in high yields and enantioselectivities is catalysed by bifunctional thiourea-cinchona alkaloids giving access to optically active nitroalcohols and aminoalcohols as final products.
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