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Updated: Jul 12, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Tetrakis(mu-benzoato-kappa2O:O)bis{[4-(dimethylamino)pyridine-kappaN1]copper(II)}
Sanchay Jyoti Bora1, Purabi Sarmah, Prodeep Phukan
1Department of Chemistry, Gauhati University, Guwahati 781 014, India.
Abstract:
The title compound, [Cu2(C(7)H(5)O(2))4(C(7)H(10)N(2))2], is a crystallographically centrosymmetric binuclear complex, with Cu atoms [Cu...Cu = 2.6982 (4) A] bridged by four benzoate ligands. Each of the Cu atoms in this bunuclear copper(II) acetate hydrate analogue is present in an approximately square-pyramidal environment, with four O atoms in a plane and the pyridine N atom at the apical site. Selected geometric parameters are compared with values for related tetrabenzoate complexes of copper(II).
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