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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
New polypyridine ligands functionalized with redox-active Fe(II) organometallic fragments
Frédéric Paul1, Sébastien Goeb, Frédéric Justaud
1Sciences Chimiques de Rennes, Université de Rennes I, CNRS (UMR 6226), Campus de Beaulieu, Bât. 10C, Rennes Cedex, France. frederic.paul@univ-rennes1.fr
Abstract:
We report in this Communication the isolation and characterization, including structure determinations, of 2,2',6',2"-terpyridine (2) and 2,2'-bipyridine (3) ligands bearing two redox-active "(eta2-dppe)(eta5-C5Me5)FeC[triple bond]C-" moieties grafted to the 5 and 5" positions of terpy or to the 5 and 5' positions of bipy. These "metalloligands" have been complexed with Ru(II) and Mo(0), providing new heterotrinuclear complexes displaying intense absorptions around 700 and 600 nm, respectively, for the Fe2Ru/terpy and Fe2Mo/bipy species. In both cases, the Fe(II)/Fe(III) oxidation potentials of the free ligands became more positive by more than 50 mV upon complexation.
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