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Updated: Jul 10, 2026
07:03
Low-energy Cathodoluminescence for (Oxy)Nitride Phosphors
Published on: November 15, 2016
Boron-oxygen luminescence centres in boron-nitrogen systems
Chengchun Tang1, Yoshio Bando, Chunyi Zhi
1Nanoscale Materials Center, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, Japan. tang.chengchun@nims.go.jp
Chemical Communications (Cambridge, England)
|November 9, 2007
Summary
Boron-nitrogen systems with closed-shell BO2(-) and BO(-) anions show promise as efficient luminescence centers. These localized anions facilitate radiation transitions for enhanced light emission applications.
Area of Science:
- Materials Science
- Solid-State Chemistry
- Luminescence
Background:
- Boron-nitrogen compounds are explored for advanced optical applications.
- Understanding luminescence centers is crucial for developing efficient light-emitting materials.
Purpose of the Study:
- To investigate the potential of closed-shell boron-oxygen anions as luminescence centers.
- To explore the role of anion localization in radiative transitions within boron-nitrogen systems.
Main Methods:
- Theoretical calculations (e.g., DFT) to model electronic structures.
- Analysis of anion localization and electronic transitions.
- Correlation of structural properties with luminescence efficiency.
Main Results:
- Closed-shell BO2(-) and BO(-) anions identified as high-efficiency luminescence centers.
- Anion localization confirmed as a key factor for radiative transitions.
- Demonstrated potential for tunable luminescence properties.
Conclusions:
- BO2(-) and BO(-) anions are promising candidates for efficient luminescence in boron-nitrogen materials.
- The localized nature of these anions is critical for achieving efficient light emission.
- Further research into these systems could lead to novel optoelectronic devices.
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