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catena-phosphorus cations.

C Adam Dyker1, Neil Burford

  • 1Dalhousie University, Department of Chemistry, Halifax, Nova Scotia B3H 4J3, Canada.

Chemistry, an Asian Journal
|December 7, 2007
PubMed
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This review covers new developments in catena-phosphorus cations, expanding fundamental phosphorus chemistry. These positively charged compounds complement existing neutral and anionic polyphosphorus structures.

Area of Science:

  • Inorganic Chemistry
  • Fundamental Phosphorus Chemistry

Background:

  • The study of polyphosphorus compounds traditionally includes neutral and anionic species.
  • A gap exists in the systematic development of positively charged phosphorus chains.

Purpose of the Study:

  • To review recent advancements in the systematic synthesis of catena-phosphorus cations.
  • To highlight the emergence of these cations as a new area in phosphorus chemistry.

Main Methods:

  • Literature review of recent synthetic methodologies.
  • Analysis of structural and chemical properties of reported catena-phosphorus cations.

Main Results:

  • Demonstration of systematic synthetic routes to various catena-phosphorus cations.

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  • Characterization of novel phosphorus chain structures with positive charge.
  • Conclusions:

    • Catena-phosphorus cations represent a developing and complementary class of polyphosphorus compounds.
    • This field offers new opportunities for fundamental phosphorus chemistry research.