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Published on: March 9, 2021
High internal phase emulsion templates solely stabilised by functionalised titania nanoparticles
Angelika Menner1, Vivian Ikem, Mariely Salgueiro
1Department of Chemical Engineering, Polymer & Composite Engineering (PaCE) Group, Imperial College London, South Kensington Campus, London, UK.
Summary
Researchers created porous polymer foams using high internal phase emulsions stabilized by titania nanoparticles. This novel method offers a new route for advanced material synthesis.
Area of Science:
- Materials Science
- Polymer Chemistry
- Nanotechnology
Background:
- High internal phase emulsions (HIPEs) are versatile templates for creating porous materials.
- Stabilization of HIPEs is crucial for controlling the final material structure.
- Titania nanoparticles offer unique properties for emulsion stabilization.
Purpose of the Study:
- To synthesize porous polymer foams using Pickering-HIPEs.
- To investigate the use of functionalised titania nanoparticles as stabilizers.
- To explore a novel templating approach for advanced porous materials.
Main Methods:
- Synthesis of poly-Pickering-HIPEs via emulsion templating.
- Utilisation of low concentrations of functionalised titania nanoparticles for stabilization.
- Characterization of the resulting porous polymer foam structures.
Main Results:
- Stable high internal phase emulsions were successfully formed.
- Porous polymer foams with controlled structures were obtained.
- Functionalised titania nanoparticles effectively stabilized the emulsions at low concentrations.
Conclusions:
- Porous polymer foams can be efficiently synthesized using poly-Pickering-HIPEs.
- Functionalised titania nanoparticles provide a robust stabilization mechanism for HIPEs.
- This method presents a promising pathway for the fabrication of advanced porous materials.

