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Superconductivity in novel Ge-based skutterudites: {Sr,Ba}pt4Ge12
E Bauer1, A Grytsiv, Xing-Qiu Chen
1Institute of Solid State Physics, Vienna University of Technology, A-1040 Wien, Austria.
Abstract:
Combining experiments and ab initio models we report on SrPt4Ge12 and BaPt4Ge12 as members of a novel class of superconducting skutterudites, where Sr or Ba atoms stabilize a framework entirely formed by Ge atoms. Below T(c)=5.35 and 5.10 K for BaPt4Ge12 and SrPt4Ge12, respectively, electron-phonon coupled superconductivity emerges, ascribed to intrinsic features of the Pt-Ge framework, where Ge-p states dominate the electronic structure at the Fermi energy.
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