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Related Concept Videos

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...
Determination of Crystal Structures01:29

Determination of Crystal Structures

In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
X-ray Crystallography02:18

X-ray Crystallography

The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
Atomic Absorption Spectroscopy: Interference01:25

Atomic Absorption Spectroscopy: Interference

Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...

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Related Experiment Video

Updated: Jul 7, 2026

Scattering And Absorption of Light in Planetary Regoliths
11:34

Scattering And Absorption of Light in Planetary Regoliths

Published on: July 1, 2019

Ice-crystal absorption: a comparison between theory and implications for remote sensing.

A J Baran, J S Foot, D L Mitchell

    Applied Optics
    |February 15, 2008
    PubMed
    Summary
    This summary is machine-generated.

    Discrepancies in cirrus crystal size measurements arise from using Mie theory inappropriately. Anomalous diffraction theory (ADT) provides more realistic retrievals, especially when considering particle habits and geometry.

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    Area of Science:

    • Atmospheric Science
    • Remote Sensing
    • Cloud Physics

    Background:

    • Discrepancies exist between remote sensing and in situ measurements of cirrus crystal sizes.
    • Inappropriate application of Mie theory is identified as a primary cause for these discrepancies.

    Purpose of the Study:

    • To investigate the reasons for disagreements in cirrus crystal size determination.
    • To compare Mie theory with anomalous diffraction theory (ADT) for cirrus cloud remote sensing.
    • To assess the influence of particle habit on infrared retrieval of crystal size.

    Main Methods:

    • Retrieved absorption optical depth at 8.3 and 11.1 µm using High Resolution Infrared Radiation Sounder (HIRS) data.
    • Applied Mie theory to ice spheres and ADT to various hexagonal and aggregate ice crystal habits.
    • Compared retrieval results with in situ measurements of tropical anvil cirrus particles.

    Main Results:

    • Mie theory yielded crystal sizes approximately one-third of those obtained with ADT.
    • ADT provided more realistic crystal size retrievals compared to in situ data.
    • Infrared retrieval of crystal size is dependent on the assumed particle habit.

    Conclusions:

    • Anomalous diffraction theory (ADT) is more suitable for retrieving cirrus crystal sizes from infrared data.
    • Particle geometry and 'tunneling' effects contribute to absorption differences between theories.
    • Future retrievals must account for particle habit to improve accuracy.