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Synthesis, Assembly, and Characterization of Monolayer Protected Gold Nanoparticle Films for Protein Monolayer Electrochemistry
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A porphyrin complex of gold(I): (phosphine)gold(I) azides as cation precursors

David V Partyka1, Thomas J Robilotto, Matthias Zeller

  • 1Department of Chemistry, Case Western Reserve University, Cleveland, OH 44106, USA.

Proceedings of the National Academy of Sciences of the United States of America
|September 11, 2008
PubMed

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Preparation of 1° Amines: Azide Synthesis01:22

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Direct alkylation of ammonia produces polyalkylated amines, along with a quaternary ammonium salt. To exclusively prepare primary amines, the azide synthesis method can be used.
Azide ions act as good nucleophiles and react with unhindered alkyl halides to form alkyl azides. Alkyl azides do not participate in further nucleophilic substitution reactions, thereby eliminating the chances of polyalkylated products. Alkyl azides are reduced by hydride-based reducing agents, like lithium aluminum...