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Published on: August 25, 2016
Temperature-triggered gate opening for gas adsorption in microporous manganese formate
Hyunuk Kim1, Denis G Samsonenko, Minyoung Yoon
1National Creative Research Initiative Center for Smart Supramolecules (CSS) and Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea. kkim@postech.ac.kr
Abstract:
Microporous manganese formate shows temperature-triggered gate opening for nitrogen and argon adsorption, which is not due to a structural change of the framework but due to dynamic opening of the pore aperture and/or sufficient kinetic energy of the adsorbates to overcome a diffusion barrier above a critical temperature.

