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Updated: Jun 29, 2026

High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
Published on: June 28, 2016
Universal link between the boson peak and transverse phonons in glass
Hiroshi Shintani1, Hajime Tanaka
1Institute of Industrial Science, University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan.
Abstract:
The physical properties of a topologically disordered amorphous material (glass), such as heat capacity and thermal conductivity, are markedly different from those of its ordered crystalline counterpart. The understanding of these phenomena is a notoriously complex problem. One of the universal features of disordered glasses is the 'boson peak', which is observed in neutron and Raman scattering experiments. The boson peak is typically ascribed to an excess density of vibrational states. Here, we study the nature of the boson peak, using numerical simulations of several glass-forming systems. We discovered evidence suggestive of the equality of the boson peak frequency to the Ioffe-Regel limit for 'transverse' phonons, above which transverse phonons no longer propagate. Our results indicate a possibility that the origin of the boson peak is transverse vibrational modes associated with defective soft structures in the disordered state. Furthermore, we suggest a possible link between slow structural relaxation and fast boson peak dynamics in glass-forming systems.
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