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Novel 1,3-diketone modified fullerenes for organic photovoltaic cells

Hak Sung Lee1, Sung Cheol Yoon, Jongsun Lim

  • 1Advanced Materials Division, Korea Research Institute of Chemical Technology (KRICT), Daejeon 305-600, South Korea.

Journal of Nanoscience and Nanotechnology
|December 4, 2008
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Structure of Conjugated Dienes01:16

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Introduction
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...