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Updated: Jun 25, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Published on: September 18, 2016

A neutral Ga(6) octahedron: synthesis, structure, and aromaticity

Brandon Quillian1, Pingrong Wei, Chaitanya S Wannere

  • 1Department of Chemistry and the Center for Computational Chemistry, The University of Georgia, Athens, Georgia 30602-2556, USA.

Journal of the American Chemical Society
|February 20, 2009
PubMed
Summary

Potassium graphite reduction of organogallium chloride yielded a gallium dimer in hexane. In toluene, the same reaction produced a neutral, aromatic gallium-6 octahedron, showcasing solvent-dependent reactivity.

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