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Published on: November 17, 2011
Identification of the antioxidation reaction products from a sinapic ester in a lipid oxidation system
Toshiya Masuda1, Jun Akiyama, Yoshio Takeda
1Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima, Japan. masuda@ias.tokushima-u.ac.jp
Abstract:
As a part of our research project on the elucidation of the chain-breaking antioxidation mechanism for natural phenols in food components, the antioxidation products from a sinapic acid methyl ester in lipid oxidation were identified. Sinapic acid is a potent antioxidative phenolic acid widely distributed in edible plants. The structural determination of the four isolated products revealed them each to have a tricyclic structure consisting of ethyl linoleate, methyl sinapate and molecular oxygen, and these were isomeric compounds for the substituents on the tricyclic moiety.
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